EFFICIENCY IN TRANSPORTING MOLECULAR OXYGEN TO IRON(II) COMPLEXES WITH LIGANDS TYPE TRI (2-PYRIDYLMETHYL) AMINE SUBSTITUTION AROMATIC IN (Α) POSITION BY A MECHANISM THAT MIMICS BIOLOGICAL OXIDATION

Dr. Nasser Thallaj


Abstract

Biological mimicry of the oxidation process of the active sites of iron proteins leads to the formation of peroxides, specifically oxygenated water, where the latter is a strong and highly satisfactory oxidizing agent, characterized by non-toxicity and low cost. In many cases, nature employs molecular oxygen for oxidative processes, particularly under extenuating conditions. Iron complexes with tris(2-pyridylmethyl)amine ligands have been studied to mimic the biologically active sites and prove their vital importance.This paper studies the possibility of obtaining iron(II) complexes with aromatic bonds of the tri-type (2-pyridylmethyl)amine on the alpha site of the nitrogen atom with testing the activity towards molecular oxygen for one complex selected from the synthesized complexes.


Keywords

Biomimetics, tri (2-pyridylmethyl)amine, activation of molecular oxygen, iron(II).


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